R2 Plus Hygienic Hard Surface Cleaner


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SAFETY DATA SHEET

Version Number: 1

R2 Plus Hygienic Hard Surface Cleaner Preparation date: 2017-07-27

1. IDENTIFICATION

Product name: Product Code: SDS #: Recommended use:
Uses advised against:

R2 Plus Hygienic Hard Surface Cleaner
5721835
MS0801249 • Industrial/Institutional •Restroom Care •DisinfectantCleaner •Thisproductisintendedtobedilutedpriortouse
Uses other than those identified are not recommended

Manufacturer, importer, supplier: US Headquarters Diversey, Inc. P.O. Box 19747 Charlotte, NC 28219-0747 Phone: 1-888-352-2249 SDS Internet Address: https://sds.diversey.com

Canadian Headquarters Diversey, Inc. - Canada 3755 Laird Road Units 8-11 Mississauga, Ontario L5L 0B3 Phone: 1-800-668-7171

Emergency telephone number:

1-800-851-7145; 1-651-917-6133 (Int'l)

2. HAZARDS IDENTIFICATION

Classification for the undiluted product

Acute oral toxicity

Category 4

Skin corrosion/irritation

Category 1B

Serious eye damage/eye irritation

Category 1

Specific target organ toxicity (repeated

Category 2

exposure)

Flammability

Flammable liquid and vapour, Category 3

Metal Corrosion:

Category 1

Signal Word:

Danger.

Precautionary Statements
FLAMMABLE LIQUID AND VAPOR. CAUSES SEVERE SKIN BURNS AND SERIOUS EYE DAMAGE. HARMFUL IF SWALLOWED. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. MAY BE CORROSIVE TO METALS. Causes burns/ serious damage to mouth, throat and stomach. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Keep only in original container. Ground/Bond container and receiving equipment. Use explosion-proof electrical, ventilating or lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe spray. Avoid contact with eyes, skin and clothing. Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wear chemical-splash goggles, chemical-resistant gloves and protective footwear. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Immediately call a Poison Center (1-800-851-7145) or physician. In case of fire: Use CO2, dry chemical, or

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foam to extinguish. Absorb spillage to prevent material damage. Store in a well-ventilated place. Keep cool. Store in corrosive-resistant container with a resistant inner liner. Dispose of in accordance with all federal, state and local applicable regulations. SUPPLEMENTAL INFORMATION:. Mix only with water. DO NOT MIX WITH BLEACH OR ANY OTHER PRODUCT OR CHEMICAL. Can react to release chlorine gas.
Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable
Classification for the diluted product @ 1:256 This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS).

Precautionary Statements None required.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Classified Ingredients
Ingredient(s) Alcohol ethoxylates n-alkyl dimethyl benzyl ammonium chloride Octyl decyl dimethyl ammonium chloride Tetrasodium salt of EDTA
Ethyl alcohol Dioctyl dimethyl ammonium chloride Didecyl dimethyl ammonium chloride
Sodium hydroxide

CAS # 68131-39-5 68424-85-1 32426-11-2
64-02-8 64-17-5 5538-94-3 7173-51-5 1310-73-2

Weight % 10 - 20% 5 - 10% 5 - 10% 3 - < 5% 3 - < 5% 3 - < 5% 3 - < 5% > 0.1 - < 1%

*Exact percentages are being withheld as trade secret information

4. FIRST AID MEASURES
Undiluted Product:
Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Skin: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water.
Most Important Symptoms/Effects: No information available. Immediate medical attention and special treatment needed Not applicable.
Diluted Product:

Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention. Skin: No specific first aid measures are required Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water.

5. FIRE-FIGHTING MEASURES

Specific methods: Suitable extinguishing media: Specific hazards:

No special methods required Not applicable. Corrosive material (See sections 8 and 10).

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Environmental precautions and clean-up methods:

Put on appropriate personal protective equipment (see Section 8.). Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up.

7. HANDLING AND STORAGE

Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Do not taste or swallow. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Absorb spillage to prevent material damage. Mix only with water. DO NOT MIX WITH BLEACH OR ANY OTHER PRODUCT OR CHEMICAL. Can react to release chlorine gas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Keep tightly closed in a dry, cool and well-ventilated place. Store in corrosive-resistant container with a resistant inner liner. Aerosol Level (if applicable) : Not applicable.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines:

.

Ingredient(s) Alcohol ethoxylates n-alkyl dimethyl benzyl ammonium chloride Octyl decyl dimethyl ammonium chloride Tetrasodium salt of EDTA
Ethyl alcohol
Dioctyl dimethyl ammonium chloride Didecyl dimethyl ammonium chloride
Sodium hydroxide

CAS # 68131-39-5 68424-85-1 32426-11-2
64-02-8 64-17-5
5538-94-3 7173-51-5 1310-73-2

ACGIH -
1000 ppm (STEL)
2 mg/m3 (Ceiling)

OSHA -
1000 ppm (TWA) 1900 mg/m3 (TWA)
2 mg/m3 (TWA)

Undiluted Product: Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels.

Personal Protective Equipment Eye protection: Hand protection: Skin and body protection: Respiratory protection:
Hygiene measures:

Chemical-splash goggles. Chemical-resistant gloves. Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Handle in accordance with good industrial hygiene and safety practice.

Diluted Product: Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels

Personal Protective Equipment Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures:

No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid Evaporation Rate: No information available Odor threshold: No information available. Melting point/range: Not determined Autoignition temperature: No information available Solubility in other solvents: No information available Density: 8.51 lbs/gal 1.02 Kg/L Bulk density: No information available
R2 Plus Hygienic Hard Surface Cleaner

Color: Clear, Dark Green Odor: Fresh Boiling point/range: Not determined Decomposition temperature: Not determined Solubility: Completely Soluble Relative Density (relative to water): 1.02 Vapor density: No information available Vapor pressure: No information available.

Not applicable

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Flash point (°F): 129.2 °F 54 °C Dilution Flash Point (°F): > 200 °F > 93.4 °C Elemental Phosphorus: 0.00 % by wt. pH: 7.25 Dilution pH: 7 @ 1:256 Corrosion to metals: Corrosive Explosion limits: - upper: Not determined - lower:

Not determined

Partition coefficient (n-octanol/water): No information available Viscosity: 0 cP VOC: 4.90 % * VOC % by wt. at use dilution 0.02 % * Flammability (Solid or Gas): Not applicable Sustained combustion: No

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY

Reactivity: Stability: Hazardous decomposition products: Materials to avoid: Conditions to avoid:

Not Applicable The product is stable None reasonably foreseeable. Oxidizing agents. Anionic surfactant. Do not mix with chlorinated products (such as bleach). No information available.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure: Skin contact, Inhalation, Ingestion, Eye contact

Delayed, immediate, or chronic effects and symptoms from short and long-term exposure Skin contact: Corrosive. Causes severe burns. Symptoms may include burns, blisters, redness and pain (which may be delayed). Eye contact: Corrosive. Causes serious eye damage. Symptoms may include pain, burning sensation, redness, watering, blurred vision or loss of vision. Ingestion: Causes burns/ serious damage to mouth, throat and stomach. Symptoms may include stomach pain and nausea. Harmful if swallowed. Symptoms may include vomiting, nausea, and/or feeling of general unwellness. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Symptoms may include coughing and difficulty breathing. Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): No information available

Carcinogen Listings: Ethyl alcohol is only classified as an IARC 1 carcinogen and California Prop 65 when it is meant for ingestion in alcoholic beverages. We do not produce alcoholic beverages; therefore it is not considered a carcinogen in our products.

Ingredient(s) Ethyl alcohol

CAS #

NTP

64-17-5

IARC -

OSHA

CA Prop 65 Carcinogen

CA Prop 65 Reproductive Developmental

Numerical measures of toxicity ATE - Oral (mg/kg): ATE - Dermal (mg/kg): ATE - Inhalatory, mists (mg/l):

1900 >5000 >20

Ecotoxicity: No information available.

12. ECOLOGICAL INFORMATION

Persistence and Degradability: No information available. Bioaccumulation: No information available.

13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food, or feed by storage or disposal.
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Waste from residues / unused products (undiluted product): This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations.
Waste from residues / unused products (diluted product): This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations.
Pesticide Storage: Refer to product label.
Pesticide Disposal: Refer to product label.
Container Disposal: Refer to product label.
RCRA Hazard Class (undiluted product): D001 Ignitable Waste. D002 Corrosive Waste. RCRA Hazard Class (diluted product): Not Regulated.
14. TRANSPORT INFORMATION
DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, http://naextranet.diversey.com/dot/, for up to date shipping information.
DOT (Ground) Bill of Lading Description: UN1903, DISINFECTANTS, LIQUID, CORROSIVE, N.O.S., (quaternary ammonium compounds), 8, III
IMDG (Ocean) Bill of Lading Description: UN1903, DISINFECTANTS, LIQUID, CORROSIVE, N.O.S., (quaternary ammonium compounds), 8, III, MARINE POLLUTANT

15. REGULATORY INFORMATION
International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA).
U.S. Regulations EPA Reg. No. : 1839-167-70627 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
HAZARD TO HUMANS AND DOMESTIC ANIMALS. DANGER: KEEP OUT OF REACH OF CHILDREN. CORROSIVE. Causes irreversible eye damage and skin burns. May be fatal if absorbed through the skin. Do not get in eyes, on skin or on clothing. Wear protective eyewear (goggles or face shield), clothing, and gloves when handling. Harmful if swallowed. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Remove contaminated clothing and wash before reuse. PHYSICAL OR CHEMICAL HAZARDS: COMBUSTIBLE. Do not use or store near heat or open flame.

CERCLA/ SARA Ingredient(s)
Sodium hydroxide

CAS # 1310-73-2

Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs)

> 0.1 - < 1%

1000

Section 313

Canadian Regulations

Ingredient(s) Ethyl alcohol
NFPA (National Fire Protection Association) Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard) Health 3 Flammability 2
R2 Plus Hygienic Hard Surface Cleaner

CAS # 64-17-5
16. OTHER INFORMATION

NPRI X
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Instability 0

Diluted Product:

Version Number: 1 Preparation date: 2017-07-27

Reason for revision: Prepared by: Additional advice:

Not applicable
NAPRAC •Containsanaddedfragrance,see"Odor"headinginsection9forspecificdescription

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

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R2 Plus Hygienic Hard Surface Cleaner